GREENEVILLE HIGH SCHOOL - CURRICULUM MAP
Subject: Advanced Placement Chemistry II
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First 4 ½ Weeks |
Second 4 ½ Weeks |
Third 4 ½ Weeks |
Fourth 4 ½ Weeks |
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CONTENT
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Chemical Fundamentals and the Structure of Matter Atomic Theory and Structure; Chemical Bonding; Nuclear Chemistry; States of Matter and the Kinetic Molecular Theory Thermochemistry |
Chemical Kinetics and Chemical Equilibrium |
Acids and Bases Applications of Aqueous Equilibria Solubility Equilibria |
ThermodynamicsElectrochemistry Review for AP Exam |
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SKILLS
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Review concepts from Chemistry I: measurements, conversions, classification of matter, formula writing, equations; Review basic stochiometric applications to problem solving; Balance oxidation-reduction equations and perform a redox titration; Apply stochiometric applications to oxidation-reduction reactions; Review quantum and wave mechanics and applications; Review electron configurations, orbital notations, and electron-dot diagrams; Discuss VSEPR theory and its application to the shapes of molecules; Discuss and illustrate the concepts of bond energy, resonance structures, and hybridization; Review gas laws and their problem applications; Review properties of solutions and colligative properties; Define the heat of solution and discuss its various energy components; Discuss Raoult’s Law and its applications; Review acid-base reactions and precipitation reactions; Discuss and apply the concepts of energy, enthalpy, and calorimetry; Apply Hess’s Law to enthalpy changes; Define and apply the first law of thermodynamics to heat calculations; Describe the energy flow between a system and its surroundings; Show how to calculate work that results from changing the volume of a gas at constant pressure; Define enthalpy and demonstrate calculations of the change in enthalpy in a chemical reaction; Show how a change in enthalpy is measured by calorimetry; Define standard states and show how to use standard enthalpies of formation to calculate standard enthalpy of formation; Discuss energy alternatives and compare the energy content of various fuels; |
Define reaction rate and show how rates can be measured from experimental data; Describe the types of rate laws; Learn methods for determining the rate law for a reaction; Develop rate laws relating to concentration to reaction time and show how they can be used to determine reaction order; Explore the relationship between the reaction pathway and the rate law; Discuss the temperature dependence of reaction rates; Describe the collision model; Define and show how to calculate activation energy; Explain how a catalyst speeds up a reaction; Discuss heterogeneous and homogenous catalysis; Determine the experimental rate law for a chemical reaction; Understand how equilibrium is established; Introduce the law of mass action and learn how to calculate values for the equilibrium constant; Discuss how the equilibrium constant is used to predict the direction a system will move to reach equilibrium; Demonstrate the calculation of equilibrium concentrations given initial concentrations; Demonstrate and practice the procedure for doing equilibrium calculations; Show how to predict the changes that occur when a system at equilibrium is disturbed; |
Discuss two models of acids and bases and relate equilibrium concepts to acid dissociation; Relate acid strength to the position of the dissociation equilibrium; Discuss the autoionization of water; Define pH, pOH, and pK and understand general methods for solving acid-base problems; Calculate percent dissociation; Calculate the pH of strong and weak acids and strong and weak bases; Apply equilibrium principles of polyprotic acids; Discuss salt hydrolysis and calculate the pH of acidic and basic salts. Use appropriate problem applicatons for concepts studied; Study the effect of a common ion on acid dissociation equilibria.; Explain the characteristics of buffered solutions; Calculate a buffer pH given the concentrations of the buffering materials; Perform appropriate calculations for pH and buffer capacity; Introduce the Henderson-Hasselbalch equation and its applications; Learn how to calculate pH at any point in an acid-base titration; Explain how acid-base indicators work; Discuss and perform titrations to illustrate strong acid-strong base, weak acid-strong base, weak base-strong acid reactions; Show how to calculate the solubility product of a salt given its solubility, and vice versa. Demonstrate the prediction of relative solubilities from Ksp values; Explain the effect of pH and a common ion on the solubility of a salt; Demonstrate how to predict if precipitation will occur when solutions are mixed; Perform appropriate laboratory experiments using the concepts;
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Define a spontaneous process; Define entropy in terms of positional probability; Discuss and apply the three laws of thermodynamics; Discuss the importance of entropy changes in the surroundings; Demonstrate and practice appropriate problem applications related to changes in entropy, enthalpy, Gibb’s free energy, and equilibrium constants. Define free energy and relate it to spontaneity; Show how to calculate the standard free energy change in a chemical reaction; Predict spontaneity of reactions; Show how the equilibrium constant related to Gibb’s free energy; Relate work to the change in free energy; Perform appropriate problem applications for concepts studied; Review the basics of oxidation-reduction reactions; Balance redox reactions using the ion-electron method; Diagram an electrochemical cell, labeling the anode, the cathode, the charges on the electrodes, and the directions of electron and ion flows; Calculate the standard emf of an electrochemical cell; Arrange given redox reagents in order of increasing strength as oxidizing and reducing agents; Predict whether a redox reaction will be spontaneous or nonspontaneous; Calculate delta G and K for a redox reaction, given Ecell value; Calculate the emf of an electrochemical cell in which the reactants and products are present at nonstandard concentrations; From a knowledge of E cell values, calculate the concentrations of a given ion in a half-cell; Diagram an electrolytic cell, showing the reactions that occur at the anode and cathode; Choose the most likely oxidation and reduction processes to be involved in the electrolysis of a given aqueous solution; Calculate the amount of a substance produced by the flow a given electrical current for a given time, or calculate the time required for a given current to produce a given amount of product; Distinguish between a galvanic and an electrolytic cell; Discuss the driving force in concentration cells; To show how to calculate equilibrium constants form cell potentials; To discuss the composition and operation of commonly used batteries; Explain the electrochemical nature of corrosion and describe some means for preventing it; Perform appropriate laboratory experiments for the units; |
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ASSESSMENT
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Exams Quizzes Laboratory applications and reports AP Practice Essays and Problems |
Exams Quizzes Laboratory applications and reports AP practice essays and problems Notebook assessment |
Exams Quizzes Laboratory applications and reports AP practice essays and problems Notebook assessment |
Exams Quizzes Laboratory applications and reports AP practice essays and problems Notebook assessment |
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RELATED LITERATURE |
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FIELD STUDIES
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TECHNOLOGY
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CD-ROM’S, Laser Discs, Videos, Laboratory Equipment, Computers, Calculators |
CD-ROM’S, Laser Discs, Videos, Laboratory equipment, Computers, Calculators |
CD-ROM’S, Laser Discs, Videos, Laboratory equipment, Computers, Calculators |
CD-ROM’S, Laser Discs, Videos, Laboratory equipment, Computers, Calculators |
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